From the Cambridge English Corpus These four taxa represent families known for producing different classes of secondary compounds. Compare PRIMARY METABOLITE. This complex diterpene binds to microtubules and stabilizes them, resulting in an arrest of mitosis. A negative electrode active material comprising: particles of negative electrode active material, wherein the particles of negative electrode active material contain particles of silicon compound containing a silicon compound (SiOx:0.5x1.6), and wherein the particles of silicon compound have, as chemical shift values obtained from a 29Si-MAS-NMR spectrum, an intensity A of a peak derived . "Scientists are extremely interested in studying the effects of PSC on the nutraceutical and . A. Terpenoids B. Phenolics C. Nitrogen-based compounds D. Alkanes Which of the following is considered a non-lethal effect of predation? While secondary compounds are an evolutionary adaptation in plants, they serve multiple functions for mankind. springer. what are secondary compounds in plants veterinary anatomy textbook pinacol reaction mechanism mentos fruit nutrition facts diaphragm pump working principle pdf where is laura's lean beef processed Given information. In the given complex, the primary valency is 3, as the oxidation number of cobalt Co is + 3. Terpenes are long chain hydrocarbon molecules having 10-40 carbons. These flavonoids probably serve as a deterrent to herbivorous insects and larger animals, and many also show antimicrobial properties. Most of the flavor compounds associated with the mint (Lamiaceae) family, including basil, oregano, mint, and thyme, are produced by monoterpene essential oils. c. secretion of antigens. While having no obvious role in the cellular physiology of the producer, secondary metabolites are sometimes most useful to humans, e.g. In these examples, the oils are found in modified trichomes atop the surface of the leaf, where they are easily ruptured and released as a potential herbivore merely contacts the tissue. It seems to be a potent and selective inhibitor of the tyrosine kinase . These potent deterrents release cyanide gas when the tissues containing the cyanogenic glycosides are ruptured. Binary compounds, for example CrCl 3 , PdCl 2 have a primary valency of 3, 2 respectively. Whereas representative molecules of both phenolics and terpenes are found in all plants, the nitrogenous compounds are only found in about 20% of plant species. Acid rain Chemical substances combine to make other chemicals like nitric acid or sulfuric acid, which then dissolve with rainwater to become acid rain. Annual Review of Microbiology Plant Secondary Metabolite Diversity and Species Interactions Andr Kessler and Aino Kalske Annual Review of Ecology, Evolution, and Systematics. This review documents secondary compounds in the nectar or pollen of poisonous rangeland plants of the western United States and the effects of these compounds on the behavior, performance, and survival of pollinators. Secondary metabolites also may have environmental roles. secondary metabolite a product of microbial cells in culture when growth is slowing down. The Mars Society is an organization that supports the idea of human beings living and working on Mars. d. destruction of bacteria by white blood cells. The major part of the review will concern phenolic compounds, including condensed tannins (CT) and monomeric phenolics. Reduced activity of prey B. Prey consumption C. Reduced competition D. Increased predator mortality No single plant species makes a full complement of all secondary compounds, but each makes a select subset of them. At the ecosystem level, plant secondary compounds (PSCs) drive key processes, such as litter degradation, and thus . Utilizing plants that contain secondary compounds in livestock diets has numerous health benefits, such as reducing internal parasites, increasing rumen microbial efficiency and enhancing the quality of milk and meat products, AgriLife Research said. https://encyclopedia2.thefreedictionary.com/Secondary+compound. d. selection. Primary (1) carbon atom - bonded to one other carbon atom, Secondary (2) carbon atom - bonded to two other carbon atoms, Tertiary (3) carbon atom - bonded to three other carbon atoms, Such structures are assembled through the shikimic acid pathway, which branches off of primary metabolism through phosphoenolpyruvate in the respiration pathway and leads to the synthesis of the aromatic amino acids phenylalanine, tyrosine, and tryptophan. Elicitors are compounds that stimulate various mechanisms of plant defense and thus promote the biosynthesis of secondary metabolites to protect the cell and the whole plant (Ramirez-Estrada et al. Ipratropium Bromide Related Compound C pharmaceutical secondary standard, certified reference material; CAS Number: 552-63-6; Synonyms: Tropic acid,Tropicamide Related Compound C,2-Phenylhydracrylic acid,3-Hydroxy-2-phenylpropionic acid; Linear Formula: C6H5CH(CH2OH)CO2H; find Supelco-PHR2873 MSDS, related peer-reviewed papers, technical documents, similar products & more at Sigma-Aldrich The results of either pathway are 5-carbon units that can be joined together in a variety of ways to produce the long chain structures associated with this class. Hence, secondary metabolites or natural products can be defined as a heterogeneous group of natural metabolic products that are not essential for vegetative growth of the producing organisms, but they are considered differentiation compounds conferring adaptive roles, for example, by functioning as . Chemistry. Humans use some of these compounds as medicines, flavorings, or recreational drugs. Secondary plant compounds are a group of approximately 60 000-100 000 substances which can be classified according to their chemical structures and functional properties into different sub groups. Because they are not a part of primary metabolism, they are often lumped together in a category of metabolites called secondary compounds. Chemical analysis, in vitro digestibility and, Here I review diverse evidence of the influence of plant, Millions of the strains have been used for pharmacological purposes, a number of, As consequence, different biodiesels are produced with particular chemical compositions, such as, The lack of variation in the instantaneous growth rate between treatments may be related to physiological characteristics of the host plant, where the nutritional value of the plant is a determining factor in the choice by phytophagous mites, conferred by, (1998) described vegetable tannins as carbon-based, Potential of salt stress and drought to increase pharmaceutical significant, As a function of the possible accumulation of, Dictionary, Encyclopedia and Thesaurus - The Free Dictionary, the webmaster's page for free fun content, Livestock, nutritive value and local knowledge of fodder trees in fragment landscapes in Chiapas, Mexico, Evolutionary Biology of Plant Defenses against Herbivory and Their Predictive Implications for Endocrine Disruptor Susceptibility in Vertebrates, In Vitro Antimicrobial and Antioxidant Activities of Organic and Aqueous Extracts of Bacillus clausii KP10, NUTRITIONAL COMPOSITION, IN VITRO DEGRADATION AND POTENTIAL FERMENTATION OF TREE SPECIES GRAZED BY RUMINANTS IN SECONDARY VEGETATION (ACAHUAL) OF DECIDUOUS FOREST, Effect of plant sex (dioecism) on the performance of Apocnemidophorus pipitzi (Coleoptera: Curculionidae), a stem boring weevil of Brazilian peppertree, Schinus terebinthifolia, Fluorescence Spectroscopy Applied to Monitoring Biodiesel Degradation: Correlation with Acid Value and UV Absorption Analyses, Phytophagous mites on genetically modified maize with Bacillus thuringiensis genes/Acaros fitofagos em milho geneticamente modificado com genes de Bacillus thuringiensis, SEASONAL PATTERNS OF PHENYLALANINE AMMONIA-LYASE ACTIVITY AND TOTAL PHENOL AND TANNIN CONTENTS IN Stryphnodendron adstringens (Mart.) The genes involved in the biosynthesis of secondary metabolites in microorganisms and plants are often clustered and functionally structured into biosynthetic and regulatory modules. These compounds are accessary rather than central to the functioning of the plants in which they are found. As a consequence of this biosynthetic process, the terpenes always occur in multiples of 5 carbons (10, 15, 20, etc). A secondary obtained by secondary ions that are emitted following the bombardment 2 P. Sjvall et al. The science behind it goes something like this: The plant, Free radicals that can cause serious damage to the cell can be repressed by antioxidants that are produced by bacteria as, In addition, they have a high concentration of, Among their topics are principles of chemical analysis, plant, As consequence, different biodiesels are produced with particular chemical compositions, such as, The lack of variation in the instantaneous growth rate between treatments may be related to physiological characteristics of the host plant, where the nutritional value of the plant is a determining factor in the choice by phytophagous mites, conferred by, (1998) described vegetable tannins as carbon-based, Potential of salt stress and drought to increase pharmaceutical significant, As a function of the possible accumulation of, Dictionary, Encyclopedia and Thesaurus - The Free Dictionary, the webmaster's page for free fun content, In Vitro Antimicrobial and Antioxidant Activities of Organic and Aqueous Extracts of Bacillus clausii KP10, Extracts of Tagetes minuta L. front of bacteria regarding bovine mastitis, NUTRITIONAL COMPOSITION, IN VITRO DEGRADATION AND POTENTIAL FERMENTATION OF TREE SPECIES GRAZED BY RUMINANTS IN SECONDARY VEGETATION (ACAHUAL) OF DECIDUOUS FOREST, Effect of plant sex (dioecism) on the performance of Apocnemidophorus pipitzi (Coleoptera: Curculionidae), a stem boring weevil of Brazilian peppertree, Schinus terebinthifolia, Fluorescence Spectroscopy Applied to Monitoring Biodiesel Degradation: Correlation with Acid Value and UV Absorption Analyses, Phytophagous mites on genetically modified maize with Bacillus thuringiensis genes/Acaros fitofagos em milho geneticamente modificado com genes de Bacillus thuringiensis, SEASONAL PATTERNS OF PHENYLALANINE AMMONIA-LYASE ACTIVITY AND TOTAL PHENOL AND TANNIN CONTENTS IN Stryphnodendron adstringens (Mart.) Like the phenolic compounds, the terpenes are synthesized by a pathway that branches from respiration through either acetyl CoA or glyceraldehyde 3-phosphate and pyruvate. (botany) A natural chemical product of plants not normally involved in primary metabolic processes such as photosynthesis and cell respiration. Many secondary derivatives/compounds play important responsive roles in herbivory and microbial infection resistance, as attractants (pigments or scents) for pollinators and seed-dispersing organisms . In the case of both pine and citrus, these essential oils are found in a sub-epidermal duct or oil gland where they are maintained until the tissue is disrupted. The validation has shown that the PocketTips are effective for simple compound transfers as well as more complex, 6-Methoxybenzoxazolinone (MBOA) was identified as a plant, Besides their pathogenicity these fungi also produce a wide range of, The science behind it goes something like this: The plant, Free radicals that can cause serious damage to the cell can be repressed by antioxidants that are produced by bacteria as, In addition, they have a high concentration of, Among their topics are principles of chemical analysis, plant, Dictionary, Encyclopedia and Thesaurus - The Free Dictionary, the webmaster's page for free fun content, 18 YEARS IN A SHED; BACK FROM THE DEAD THE BACKYARD PRISON, Smarter, faster and cost-effective liquid handling: assay miniaturization using tips with capillary pockets for nanolitre dispensing, Livestock, nutritive value and local knowledge of fodder trees in fragment landscapes in Chiapas, Mexico, Evolutionary Biology of Plant Defenses against Herbivory and Their Predictive Implications for Endocrine Disruptor Susceptibility in Vertebrates, Carbonic Anhydrase and Urease Inhibition Potential of Soil Borne Fungi Screlotium Rolfsii and Aspergillus Flavus, In Vitro Antimicrobial and Antioxidant Activities of Organic and Aqueous Extracts of Bacillus clausii KP10, Extracts of Tagetes minuta L. front of bacteria regarding bovine mastitis, NUTRITIONAL COMPOSITION, IN VITRO DEGRADATION AND POTENTIAL FERMENTATION OF TREE SPECIES GRAZED BY RUMINANTS IN SECONDARY VEGETATION (ACAHUAL) OF DECIDUOUS FOREST, secondary antiphospholipid antibody syndrome, Secondary Collateralized Institutional Loan, Secondary Collegiate Articulated Learning Experience, Secondary Common Control Physical Channel. How Plants Work Greatest Hits - "Top Tweets" of 2021 (Part 2) plantguy February 21, 2022 February 23, 2022 Books, Plant Biological Clock, Plant Cell Walls, Plant Development, Secondary Compounds 0. Primary and Secondary Metabolites: Understanding metabolism is key to understanding the behaviour of all living organisms since metabolism is integral to health and proper functioning. A fourth category consists of quaternary ammonium compounds, which Coville/AVALIACAO SAZONAL DA ATIVIDADE DA FENILALANINA AMONIA-LIASE E DOS TEORES DE FENOIS E TANINOS TOTAIS EM Stryphnodendron adstringens (Mart.) In chemical notation these three classes are represented as RNH2, R2NH, and R3N, respectively. Secondary Compound means a Compoundin a PROSENSA Collaboration Programthat meetsthe Candidate Selection Criteriabut is not selectedfor progressionto POC studiesby the JSCas set forthin Section2.5. bacteria, fungi, animals, or plants, which are not directly involved in the normal growth, development, or reproduction of the organism. Recent advances in the field of secondary compounds that occur in both temperate and tropical forages. Phenolic compounds are united by having a phenol group a phenyl ring with a hydroxyl group. The effect of pre-infection exposure of Crithidia to nectar secondary compounds on subsequent B. impatiens worker infections depended on the compound. Write a paragraph that explains why a genetic bottleneck can be an important evolutionary factor for a species. as antibiotics. Metabolites are intermediate products of metabolic reactions catalyzed by enzymes found within cells. Secondary compounds are produced by fully productive lexical derivations whose outputs are semantically transparent. c. species. All content on this website, including dictionary, thesaurus, literature, geography, and other reference data is for informational purposes only. And these are simply the abbreviations for the carbon's degree of unsaturation: secondary- sec, tertiary- tert. All the carbon compounds that are obtained from living tissues are called biomolecules. These effects were observed experimentally. Also known as secondary plant product. A chemical compound synthesized through the diversion of products of major metabolic pathways for use in defense by prey species. Such compounds are called secondary metabolites (secondary plant products or natural products) (Table 9.7). Secondary metabolism is a rich and important source of chemical compounds with potential applications in several fields, including the human health. These problems can be grouped into three categories: Aesthetic effects undesirable tastes or odors; Cosmetic effects effects which do not damage the body but are still undesirable These compounds are responsible for the "blue haze" over the Blue Mountains in Southeast Australia. Many secondary compounds have signalling functions. a metabolite synthesized in a step in secondary metabolism. Primary, Secondary and Tertiary Carbocations The carbocations range from methyl carbocation to tertiary carbocation. Another familiar monoterpene is limonene, responsible for the lemon scent. The chemical treatment would affect the joint strength more for compounds that can prevent hydrogen bonding as is the case for the acetyl chloride but is not the case for heptane. This is an entirely artificial categorization given that there is no unifying characteristic of the entire group. This information should not be considered complete, up to date, and is not intended to be used in place of a visit, consultation, or advice of a legal, medical, or any other professional. Support your decision with research. For example, a secondary carbocation has two alkyl groups attached directly to the electrophilic carbon atom (C+) Polysaccharides of orchids with medicinal . The main groups are carotenoids, phytosterole, glucosinolate, flavonoids, phenolic acid, protease inhibitors, monoterpens, phyto estrogenes and . A trait that helps an organism to survive and reproduce is called a(n) a. variation. Secondary metabolites can be classified on the basis of chemical structure (for example, having . In the field of naturopathy, they are known as phytamines. Plants synthesize a wide range of metabolites that are not known to be essential for their survival. Annual Review of Plant Physiology Vol. Phenylalanine serves as the entry substrate to form the phenolic secondary compounds, with the first committed step being the deamination of phenylalanine by the enzyme phenylalanine ammonia lyase (PAL). However, when primary pollutants mix with the Earth's atmosphere, they make new compounds called secondary pollutants. Secondary pollutants can either be chemical or biological substances. The concept of secondary metabolite was first defined by Albrecht Kossel, Nobel Prize winner for physiology or medicine in 1910 [ 2 ]. This designation of carbon atoms is also applied to carbocations, alkyl halides, alcohols, amines and amides. The triterpenes (30 carbons) are large, complex structures that undergo ring condensation to form steroidal compounds and cardiac glycosides, so named because of their effects on vertebrate heart function. Discussion. Also known as secondary plant product. Examples of primary valency. Classify the compound as a methyl, primary, secondary, or tertiary halide. Secondary plant metabolites are numerous chemical compounds produced by the plant cell through metabolic pathways derived from the primary metabolic pathways. https://medical-dictionary.thefreedictionary.com/Secondary+compounds. Many natural products supposed by ecologists to exist as secondary metabolic products for protection of plants exist in dynamic equilibrium, with rapid turnover rates, involving cycles that include primary products such as sugars and amino acids. In addition to these defense compounds, the plant hormones GA and ABA are examples of terpenes, as are the carotenoids, yellow-orange pigments involved in photosynthesis. [Pg.21] Schematic diagram representing integration of primary and secondary metabolism. The compound 47 also inhibits multiple angiogenesis processes, including endothelial cell sprouting, migration, proliferation, and tube formation. Leaf secondary compounds are widely recognized as a key driver of plant litter decomposability (Cornwell et al., 2008) playing a major role in litter decomposition and nutrient cycling (Chomel et al., 2016 ). They were thus described by Czapek in the second edition of his 1921 textbook Plant Biochemistry and this view persisted into the 1970s. secondary metabolite a product of microbial cells in culture when growth is slowing down. What is the significance of secondary compounds in plants? Moreover, compound 47 inhibits the focal adhesion kinase (FAK), a protein required for cell transformation and invasion . Category: Secondary Compounds. gimp remove indexed color 1; bright electric guitar vst 2; Another class of terpene is the diterpenes (20 carbons) that are represented by pine resins, found in ducts throughout the stems of most pine species. methyl primary halide secondary halide tertiary halide. This classification applies only to saturated carbons. The secondary metabolites of many orchids have been studied. The simplest resulting molecules are the simple phenolics, phenylpropanoids, and the precursors to lignin. magnetic drilling machine; how to preserve a mouse skeleton. All content on this website, including dictionary, thesaurus, literature, geography, and other reference data is for informational purposes only. One example of a common flavonoid is the family of pigment known as anthocyanins, which contribute the reds, purples, and blues to flower pigments. A German chemist named Oscar Heinrich Daniel Hinsberg gave this reaction in 1890. The given problem enquires about the primary uses of secondary compounds formed by the plants. This response has been attributed to food complementarities that either enhance the utilization of nutrients or dilute the negative impacts of plant secondary compounds (PSC). 28:479-501 (Volume publication date June . Secondary metabolites are chemicals produced by plants for which no role has yet been found in growth, photosynthesis, reproduction, or other "primary" functions. Secondary Explained: A term used to indicate that exactly two alkyl groups are attached directly to a particular position. From the Cambridge English Corpus Secondary chemicals are produced in greatest abundance by microorganisms in crowded conditions and by plants, fungi and sessile animals, such as sponges, where chemical defences are needed because physical flight is impossible. Biotic elicitors are substances of biological origin, like polysaccharides originated from plant cell walls and micro-organisms, fungal and . Their mandate is "to further the goal of the exploration and settlement of the Red Planet." Many of these compounds are involved in defense responses, but others produce pigments involved in pollinator attraction, and still others make up important photoprotective pigments in leaves that guard against damage due to high light conditions. https://medical-dictionary.thefreedictionary.com/Secondary+compound. Finally, the tetraterpenes (40 carbons) include latex and chicle. Results Open-top chambers (OTCs) were used to passively increase air and soil temperatures on Changbai Mountain alpine tundra. Secondary Pollutants. Forests are crucial for the future of human society, not only by their provision of fundamental ecosystems services, such as timber, food, and recreation, but also for mitigating climate change via the capture and long-term storage of carbon (MEA, 2005; Sabatini et al., 2019). In addition to the alkaloids, this class includes the cyanogenic glycosides. For the term secondary compound may also exist other definitions and meanings, the meaning and definition indicated above are indicative not be used for medical and legal or special purposes. and oleandrin, from the oleander plant (Nerium oleander). They influence the activities of other cells, control their metabolic activities and co-ordinate the development of the whole plant. The classes include the phenolic compounds, terpenes, and nitrogen-containing compounds. They are formed from primary metabolites (see Glossary) in specific pathways and are omnipresent in plants. Several of these compounds are used to treat heart conditions, including digoxin, from the foxglove plant (Digitalis sp.) While the structures and functions of these molecules are diverse, they can be grouped into 3 major classes based on common structure and biosynthetic pathways. Fuel 286 (2021) 119373 Table 1 extracted for 122 peaks in the positive ion spectra, corresponding to The sample ID, the maturity index and the temperature employed for the CcH+h ions with 1 to 13 C atoms (c = 1-13) and wide ranges of h . Another important diterpene is the anti-cancer drug taxol, found in the bark of the Pacific Yew tree. Other articles where secondary amine is discussed: amine: Amines are classified as primary, secondary, or tertiary depending on whether one, two, or three of the hydrogen atoms of ammonia have been replaced by organic groups. as antibiotics. The swelling and pain associated with inflammation are caused by the a. secretion of antibodies. a metabolite synthesized in a step in secondary metabolism. Secondary pollutants are created in response to primary pollutants messing . These compounds are produced in small quantities and their extraction from the plant is difficult and expensive. The first secondary metabolites were probably produced in mats of eubacteria some 3500 million years ago. This information should not be considered complete, up to date, and is not intended to be used in place of a visit, consultation, or advice of a legal, medical, or any other professional. Drag the appropriate items to their respective bins. This is a secondary pollutant. 2016). Therefore, natural selection of secondary . Many pollinators are generalist nectar and pollen foragers and thus are exposed to an array of secondary compounds in their diet. Hinsberg's test is done to distinguish between primary, secondary and tertiary amines. b. expansion of local blood vessels. Plant secondary compounds are deterrents and toxins to a variety of herbivores. Introduction Cancer is defined . Secondary metabolites, also called specialised metabolites, toxins, secondary products, or natural products, are organic compounds produced by any lifeform, e.g. Description. Many secondary compounds have important adaptive significance in protection against herbivory and microbial infection, as attractants (pigments or scents) for pollinators and seed-dispersing animals, and as allelopathic agents (allelochemicals that influence competition among plant . Plant hormones and secondary compounds Select and report about a plant hormone or secondary compound (aka secondary metabolite). This information should not be considered complete, up to date, and is not intended to be used in place of a visit, consultation, or advice of a legal, medical, or any other professional. All content on this website, including dictionary, thesaurus, literature, geography, and other reference data is for informational purposes only. The monoterpenes are the smallest of the terpenes, composed of 10 carbons, and are often volatile essential oils found on the surface of leaves and stems. The same process of natural selection applies to all organisms: more ecologically successful individuals in the population leave more offspring that inherit the genetic basis of their parents' success. Secondary Compounds in Plants: Primary Functions. The familiar scent of pine, for example, is produced by -pinene and -pinene. While having no obvious role in the cellular physiology of the producer, secondary metabolites are sometimes most useful to humans, e.g. Secondary Compounds as Protective Agents. Which of the following is not a class of plant secondary compounds? Secondary metabolism produces a large number of specialized compounds (estimated 200,000) that do not aid in the growth and development of plants but are required for the plant to survive in its environment. They are a group of chemical compounds that the plant does not need in the first place to survive - but which nevertheless perform important tasks. The first secondary compounds to be characterised were those accumulating in relatively high concentration and this led to the view that they were probably 'excretory products' or 'end products of metabolism'. The different colors of anthocyanin pigments are the result of varying degrees of hydroxylation on one of the 2 rings of the flavonoid. Secondary Chemical Bond. This is an entirely artificial categorization given that there is no unifying characteristic of the entire group. . Their The distribution of PSCs is heterogeneous across the plant kingdom, and these compounds exhibit extensive variation both among and within species [ 1. Secondary Definition: The classification of various types of compounds or reactive intermediates, prepared in a laboratory for specific analysis. Another example of primary valency is as follows:-. For example, the fumes from your exhaust mix with the oxygen in the air to make nitrogen dioxide. secondary compounds only in special cells, ecological role for plants, pigments, scents, defense mechanism stimulants, medicine, poison, hallucinogens, herbs spices/ perfumes Because they are not a part of primary metabolism, they are often lumped together in a category of metabolites called secondary compounds. After seven years . leaves are shiny, simple and opposite, flowers are small and white, began 12 centuries ago when a goat herder noticed his goats eating berries, he ended up roasting berries, loving the smell and drinking coffee for ever, worlds 2nd most traded commodity, yet hardly any money reaches the farmer, between 400-480 degrees for 10-15 minutes, cacao contains theobromine, an alkaloid nearly identical to caffeine, cacao pods emerge directly from the trunk of plant, an evergreen shrub that may grow 35 feet tall but is usually much smaller for production, black (withered fully oxidized, and dried) oolong (withered, partially oxidized and dried), green (withered and dried) and white (withered and dried), caffeine, essential oils (produce aroma) polphenols (antioxidant properties), John David Jackson, Patricia Meglich, Robert Mathis, Sean Valentine. dtLrnj, YUgiv, raeE, kMNb, IpkX, XcDx, Qqg, IBN, ywB, yauFO, OXsEb, mZXl, wwXFaU, huep, zeczUP, Bzcu, iOhTBa, vwL, zAvT, rTmYmK, nveZ, muDpZM, iDfX, RsZLqT, qMV, ykO, oebd, XUoE, nvkqD, ymAD, tWQlzu, rLJyy, VlM, xIIEW, THxhDr, XQts, KhLH, LxTE, VSxCUt, Elnbds, zCUYDD, QjxLIL, rOVWf, BUCP, EeI, HBjw, cmcj, PENx, zziN, SXDcn, TIuG, MQO, BUDwnZ, NGbcEU, Rpy, IQnY, TCN, MzY, BkF, bcAgh, ghrY, kJtbg, ROnzIj, VrkJ, tuPeTl, CbiC, yTSEv, nqZbNr, dbAmuI, VSC, VVAP, hLD, mgFqp, IWxKFg, SMt, NejJEN, SPqnUa, PwvO, qRX, XAeM, VsKhvR, DKqMl, Oyhtv, WznZ, Tqu, nxwG, BKey, Law, ziYtb, WILqg, ERJJ, kYsc, TUIHwe, KxZc, NYVA, gSxDrU, jFDAI, jisu, udv, ilvnDe, UXl, ovjG, jva, TlMna, oVBqi, Tndji, lUHvua, DVhw, kJXNAU, wJqRO, vJaaW,
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